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extraction molybdenum selective

Selective liquid-liquid extraction of molybdenum (VI) and ...

2020-1-1  A study on the selective solvent extraction (SX) of Molybdenum (Mo) and Rhenium (Re) from a synthetic pregnant leach solution (PLS) has been carried out using two diluents: kerosene and the ionic liquid (IL) 1-octyl-3-methylimidazolium bis(trifluoromethylsufonyl)imide ([omim][Tf2N]) and two extractants: di(ethylhexyl)phosphoric acid (D2EHPA) and the IL trioctylmethylammonium bis(2-ethylhexyl)

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Selective extraction of molybdenum from copper concentrate ...

2017-5-1  Therefore, molybdenum was selectively leached to separate from copper concentrate. The leaching conditions are: sodium hydroxide 2.0 mol/L, liquid to solid ratio 6/1 mL/g, leaching temperature 70 °C and ventilation volume 0.6 m 3 /h. Under these conditions, the extraction of Mo reached 93.5% after leaching for 8 h.

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Extraction and selective stripping of molybdenum(VI) and ...

Molybdenum(VI) and vanadium(IV) were extracted preferentially and separated completely from the coexisting metals involved at low pH (e.g., around 1.5) with LIX 63 dissolved in Exxsol D80. Vanadium(IV) in the loaded organic phase was selectively stripped by contacting with a 2 M sulfuric acid solution and isolated from molybdenum(VI).

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Selective extraction of molybdenum from acidic leach ...

Molybdenum is selectively extracted from an aqueous solution containing various other metal values, e.g. copper, arsenic, iron, bismuth, antimony, tin, and lead in addition to molybdenum. The molybdenum-bearing solution is adjusted to a pH of about 2.0 or less, and, then, intimately contacted with an organic extracting solution containing an ...

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Method for the selective extraction of molybdenum and

The invention relates to the production of highly pure compounds molybdenum and bismuth from various raw materials. In the method for the selective extraction of molybdenum and bismuth conduct leaching of molybdenum and bismuth chloride solutions, sorption of bismuth on the anion exchange resin, the desorption of bismuth.

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Selective extraction of molybdenum and vanadium from

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic United States Patent 4666685

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Selective Recovery of Molybdenum over Rhenium from ...

2020-11-4  Selective extraction of rhenium over molybdenum from alkaline solutions has also been studied by employing an organic phase composed of 20% N235 and 30% TBP diluted in kerosene. An organic phase composed of 5 vol% N235 (in kerosene) was found to selectively recover Re over Mo at equilibrium pH 0.0.

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Separation of tungsten and molybdenum using selective ...

2020-12-1  The addition of tributyl phosphate (TBP) promotes significant improvement of phase separation, where an increase in molybdenum extraction is observed from 75% to 87% with increasing TBP concentration (Zeng et al., 2015). Not only can the additives complex with organic substances in the solvent extraction method, but also can complex with metal ions to improve the separation effect.

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Mechanism of Selective Precipitation of Molybdenum from ...

Selective precipitation of molybdenum (Mo) is a widely utilized method for separation of Mo from tungstate solution; however, the corresponding mechanism is still unclear.

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(PDF) Thiophosphinic acids as selective extractants for ...

Thiophosphinic acids as selective extractants for molybdenum recovery from a low grade ore and spent catalysts

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Method for the selective extraction of molybdenum and

In the method for the selective extraction of molybdenum and bismuth conduct leaching of molybdenum and bismuth chloride solutions, sorption of bismuth on the anion exchange resin, the desorption of bismuth. Before adsorption of bismuth spend the sorption of molybdenum and other heavy metals in phosphate-acidic cation exchanger at pH 0.0 to 0.5 ...

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US4026988A - Selective extraction of molybdenum from ...

Molybdenum is selectively extracted from an aqueous solution containing various other metal values, e.g. copper, arsenic, iron, bismuth, antimony, tin, and lead in addition to molybdenum. The molybdenum-bearing solution is adjusted to a pH of about 2.0 or less, and, then, intimately contacted with an organic extracting solution containing an alpha-hydroxy oxime.

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US4666685A - Selective extraction of molybdenum and ...

Selective extraction of molybdenum and vanadium from spent catalysts by oxidative leaching with sodium aluminate and caustic Download PDF Info Publication number US4666685A. US4666685A US06/861,689 US86168986A US4666685A US 4666685 A US4666685 A US 4666685A US 86168986 A US86168986 A US 86168986A US 4666685 A US4666685 A US 4666685A

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(PDF) Selective Recovery of Molybdenum over Rhenium from ...

2020-10-26  Selective solvent extraction of molybdenum over rhenium from molybdenite (MoS2) flue dust leaching solution was studied. In the present work,

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Liquid-liquid extraction of molybdenum thiocyanate with ...

A sensitive and selective method for estimation of trace molybdenum with fairly common reagents has been developed. The Mo-thiocyanate complex is extracted with hexamethyl phosphortriamide and chloroform from 0.75-1.5M hydrochloric acid. The molar absorptivity is 1.76 x 10(4) 1.mole(-1).cm(-1). The system obeys Beer's law at 460nm over the molybdenum concentration range 0.75-5ppm.

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Extraction and separation of molybdenum and vanadium

Extraction of vanadium and molybdenum from alkaline leaching solution of boiler ash was investigated. The ash coming from heavy oil-fired electrical power station was leached with 8 mol dm^-3 sodium hydroxide at 373 K. The leaching solution was cooled to 278 K; an alkali-precipitate was precipitated. The precipitate was dissolved in sulfuric acid and a selective solvent extraction process was ...

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Mechanism of Selective Precipitation of Molybdenum from ...

Abstract. Selective precipitation of molybdenum (Mo) is a widely utilized method for separation of Mo from tungstate solution; however, the corresponding mechanism is still unclear. The aim of the ...

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Separation of vanadium and molybdenum from aqueous ...

2019-10-24  The separation of vanadium (V) and molybdenum (VI) was studied by co-extraction with an aqueous two-phase system formed by PEG2000 + sodium sulfate + water and by selective stripping with another aqueous two-phase system formed by ammonium sulfate solution and PEG2000 phase loaded vanadium and molybdenum. The effect of aqueous pH, concentration of vanadium and molybdenum,

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Preparation of a New Solid-State Molybdenum-Selective ...

A new solid state molybdenum-selective electrode has been developed. The electrode is composed of 20% MoS2, 60% Ag2S, and 20% Cu2S. An analytically useful potential change occurred, from 1 × 10-5 to 1 × 10-1 M molybdenum ion. The slope of the linear portion (1 × 10-1 - 1 × 10-5 M) was about 45 ± 2 mV/10-fold concentration changes in molybdenum.

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Separation of tungsten and molybdenum with solvent ...

2021-6-15  Functionalized ionic liquids (FILs) as extradants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time. The effects of initial pH, extractant concentration, metal concentrations in the feed were comprehensively investigated. The results showed that tricaprylmethylammonium bis(2,4,4-tiimethylpentyl)phosphinate ([A336][Cyanex272]) could ...

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Method of extraction of molybdenum from molybdenum ...

FIELD: petrochemical industry; methods of the selective extraction of molybdenum from the solutions containing molybdenum and vanadium. SUBSTANCE: the invention is pertaining to the method of the selective extraction of molybdenum from the liquid mixtures, in which molybdenum is present with vanadium at the amount of molybdenum exceeding (200) mg/l.

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Extraction of molybdenum as an added value in steel ...

2017-8-1  In the second step, a selective leaching of molybdenum was designed and tested. Step 2 showed that molybdenum can be efficiently leached with a low concentration of hydroxide and that the liquid does not need to be heated. After leaching, molybdenum can be separated from contaminating metals, mainly zinc, with conventional liquid extraction.

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SELECTIVE EXTRACTION OF VANADIUM (V) FROM

2007-3-30  (1992). SELECTIVE EXTRACTION OF VANADIUM (V) FROM SOLUTIONS CONTAINING MOLYBDENUM (VI) BY AMMONIUM SALTS DISSOLVED IN TOLUENE. Solvent Extraction and Ion Exchange: Vol. 10, No. 4, pp. 623-635.

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Liquid-liquid extraction of molybdenum thiocyanate with ...

A sensitive and selective method for estimation of trace molybdenum with fairly common reagents has been developed. The Mo-thiocyanate complex is extracted with hexamethyl phosphortriamide and chloroform from 0.75-1.5M hydrochloric acid. The molar absorptivity is 1.76 x 10(4) 1.mole(-1).cm(-1). The system obeys Beer's law at 460nm over the molybdenum concentration range 0.75-5ppm.

More

Extraction and separation of molybdenum and vanadium

Extraction of vanadium and molybdenum from alkaline leaching solution of boiler ash was investigated. The ash coming from heavy oil-fired electrical power station was leached with 8 mol dm^-3 sodium hydroxide at 373 K. The leaching solution was cooled to 278 K; an alkali-precipitate was precipitated. The precipitate was dissolved in sulfuric acid and a selective solvent extraction process was ...

More

Separation of vanadium and molybdenum from aqueous ...

2019-10-24  The separation of vanadium (V) and molybdenum (VI) was studied by co-extraction with an aqueous two-phase system formed by PEG2000 + sodium sulfate + water and by selective stripping with another aqueous two-phase system formed by ammonium sulfate solution and PEG2000 phase loaded vanadium and molybdenum. The effect of aqueous pH, concentration of vanadium and molybdenum,

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Separation of tungsten and molybdenum with solvent ...

2021-6-15  Functionalized ionic liquids (FILs) as extradants were employed for the separation of tungsten and molybdenum from a sulfate solution for the first time. The effects of initial pH, extractant concentration, metal concentrations in the feed were comprehensively investigated. The results showed that tricaprylmethylammonium bis(2,4,4-tiimethylpentyl)phosphinate ([A336][Cyanex272]) could ...

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Nano-MoO3 for highly selective enrichment of polycyclic ...

2019-9-21  Nano-molybdenum trioxide was used as the extraction coating on the stainless steel wire. Four wires were filled in a polyetheretherketone tube to get an extraction tube. The tube was connected to the six-port valve of a high performance liquid chromatograph, and the

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Evaluation of molybdenum recovery from sulfur removed ...

2020-2-6  The solvent extraction followed by the stripping technique was found to be excellent as the concentration of vanadium and molybdenum enriched from

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Study on Leaching of Molybdenum from a Spent HDS

The aim of this study is to investigate the extraction of molybdenum from the spent HDS catalyst. The experiment was performed by using the pyro-hydrometallurgical process; calcination and leaching. The spent catalyst was calcined at different temperatures in order to investigate the effect of calcination temperature on the recovery of molybdenum in the subsequent process.

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